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Single crystals of Metal-Organic Framework Ulm-4 grown selectively on a micro-structured plasma polymer coating

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Abstract A multilayer plasma polymer coating was deposited on small glass discs and afterwards treated with ultra violet radiation through a patterned mask to generate a micro-structured substrate with an… Click to show full abstract

Abstract A multilayer plasma polymer coating was deposited on small glass discs and afterwards treated with ultra violet radiation through a patterned mask to generate a micro-structured substrate with an alternating hydrophilic/hydrophobic surface. The substrate was then immersed in a mother liqueur of the porous, functional material Metal-Organic Framework Ulm-4 (MFU-4) to preferentially grow crystals on the hydrophilic areas of the film. X-ray diffraction and electron microscope analysis showed the formation of MFU-4 single crystals.

Keywords: polymer coating; organic framework; micro structured; plasma polymer; framework ulm; metal organic

Journal Title: Thin Solid Films
Year Published: 2019

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