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Corrosion-erosion behaviour and mechanisms of in-situ transformed Cf/Al2O3 Composite

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Abstract The corrosion-erosion behaviour and mechanisms of in-situ transformed carbon fiber reinforced alumina ceramic matrix composite (C f /Al 2 O 3 ), homemade alumina (H-Al 2 O 3 )… Click to show full abstract

Abstract The corrosion-erosion behaviour and mechanisms of in-situ transformed carbon fiber reinforced alumina ceramic matrix composite (C f /Al 2 O 3 ), homemade alumina (H-Al 2 O 3 ) and commercial alumina (C-Al 2 O 3 ) were investigated by a modified MSH tester. The both in-situ C f /Al 2 O 3 and H-Al 2 O 3 were fabricated by hot-press sintering in vacuum. The corrosion-erosion experiments for the three kinds of specimens were conducted respectively in 20 vol% SiC slurry of pH 2, 7 and 12 at speed of 3.67–5.76 m/s for 120 min. The static and dynamic soaking corrosion experiments at different pH solutions were also carried out. In the static soaking corrosion experiments, the in-situ C f /Al 2 O 3 exhibited better corrosive resistance than H-Al 2 O 3 and C-Al 2 O 3 in pH 2 acid solution, but in pH 12 alkaline solution the mass loss of three materials was very slight. The corrosion mechanism in pH 2 solution is the dissolution of bonding phase between Al 2 O 3 particles. In corrosion-erosion tests, the corrosion-erosion loss rate of three materials increases with velocity. The corrosion-erosion loss rate of in-situ C f /Al 2 O 3 is less than that of C-Al 2 O 3 in pH 2 slurry, but slight higher than that of C-Al 2 O 3 in pH 7 and 12 slurries. The corrosion-erosion rate of in-situ C f /Al 2 O 3 is less than that of H-Al 2 O 3 in all tested pH slurries. Due to the bonding phase dissolution of C-Al 2 O 3 in pH 2 slurry, the bonding strength between Al 2 O 3 particles weakens, which promotes the interaction between corrosion and erosion, therefore the loss rate of C-Al 2 O 3 is higher than that of in-situ C f /Al 2 O 3 . The effects of carbon fibers on the corrosion-erosion are absorbing the impact energy by debonding and bridging toughening mechanism and inhibiting the cracks propagating, as well as the weak interaction of corrosion and erosion, which result in the better wear resistance of the in-situ C f /Al 2 O 3 at pH 2.

Keywords: erosion behaviour; behaviour mechanisms; corrosion; mechanisms situ; corrosion erosion

Journal Title: Wear
Year Published: 2017

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