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Recovery of magnetite from waste ferrous sulfate using polyethylene glycol (PEG) as a dispersant

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Abstract The effect of PEG dispersant on the magnetic separation of magnetite (Fe3O4) synthesized from ferrous sulfate solution via co-precipitation method with calcium hydroxide as the precipitant was investigated. The… Click to show full abstract

Abstract The effect of PEG dispersant on the magnetic separation of magnetite (Fe3O4) synthesized from ferrous sulfate solution via co-precipitation method with calcium hydroxide as the precipitant was investigated. The results indicated that a PEG dispersant could significantly affect Fe3O4 recovery. Adding PEG during the preparation of Fe3O4 was unfavorable for Fe3O4 recovery. When the PEG-6000 concentration was increased from 0 to 8 g/L, the iron grade and median particle size of the Fe3O4 product decreased from 65.58% and 2.35 μm to 57.79% and 1.35 μm, respectively. However, adding PEG during the wet milling of the mixed product promoted the subsequent recovery of Fe3O4. When the amount of PEG-200 increased from 0% to 4% of the powder mass, the grade of iron in the Fe3O4 product increased from 65.58% to 68.32%. While the relative molecular mass of PEG at an amount of 4% of the powder mass increased from 200 to 20000, the grade of iron was reduced from 68.32% to 66.70%.

Keywords: recovery; recovery magnetite; peg dispersant; ferrous sulfate; peg

Journal Title: Transactions of Nonferrous Metals Society of China
Year Published: 2018

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