Abstract Deep eutectic solvents (DESs) are a kind of potential lixiviant for selective metal processing due to their versatile complexation properties. In this study, we investigated the recovery of zinc… Click to show full abstract
Abstract Deep eutectic solvents (DESs) are a kind of potential lixiviant for selective metal processing due to their versatile complexation properties. In this study, we investigated the recovery of zinc from zinc oxide dust using choline chloride−urea− ethylene glycol (ChCl−urea−EG) DESs. The zinc extraction efficiency can be up to 85.2% when the slurry concentration is 50 g/L, leaching temperature is 80 °C and stirring speed is 600 r/min. The leaching process is controlled by the diffusion and the corresponding activation energy is 32.1 kJ/mol. The resultant solution was directly used for the electrodeposition of zinc. The pure zinc deposit is obtained with a current efficiency of 82.6%. Furthermore, the ChCl−urea−EG DESs can be recycled. This approach is shown to be promising for the recycling of zinc from the zinc-containing dust.
               
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