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Abstract A novel nitrogen-centered radical-induced 1,2-carbon migration reaction of allylic alcohols has been developed. This method provides easy access to a variety of α-quaternary-β-amino ketones under mild reaction conditions. The… Click to show full abstract
Abstract A novel nitrogen-centered radical-induced 1,2-carbon migration reaction of allylic alcohols has been developed. This method provides easy access to a variety of α-quaternary-β-amino ketones under mild reaction conditions. The reaction has a wide substrate scope and operational simplicity. Mechanistic studies suggest that 1,2-carbon migration is induced by regioselective nitrogen-centered radical addition to the alkene unit.
Keywords:
amino ketones;
quaternary amino;
carbon;
allylic alcohols;
carbon migration
Journal Title: Chinese Journal of Catalysis
Year Published: 2018
Link to full text (if available)
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Journal Title: Chinese Journal of Catalysis
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!