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Abstract Rh(III)-catalyzed, chelation-assisted oxidative C−H imidation of arenes with N−H imide have been realized using PhI(OAc)2 as an oxidant. This transformation exhibits a broad substrate scope and tolerates various functional… Click to show full abstract
Abstract Rh(III)-catalyzed, chelation-assisted oxidative C−H imidation of arenes with N−H imide have been realized using PhI(OAc)2 as an oxidant. This transformation exhibits a broad substrate scope and tolerates various functional groups. The reaction proceeded via in situ generation of an iodine(III) imido. DFT calculations suggest that this oxidative imidaton system proceeds via a Rh(III)-Rh(V)-Rh(III) pathway.
Keywords:
iii;
chelation assisted;
catalyzed chelation;
iii catalyzed;
imidation arenes
Journal Title: Chinese Journal of Catalysis
Year Published: 2020
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Journal Title: Chinese Journal of Catalysis
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!