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Using HR-TEM for Geological Environment Investigation: A Case Study of Silver Nanoparticles Associated with Mine Waste in a World Heritage Site

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The New Caledonian archipelago, located approximately 2,000 km east of Australia, is home to one of the world’s largest ophiolite complexes – uncommon rock units approximating those found in the… Click to show full abstract

The New Caledonian archipelago, located approximately 2,000 km east of Australia, is home to one of the world’s largest ophiolite complexes – uncommon rock units approximating those found in the Earth’s mantle. New Caledonia has the 3 largest nickel reserve in the world and ranks 5 in global production [1]; nickel is mined from enriched clay minerals formed during tropical weathering the ophiolite underwent since emplacement 35 million years ago [2]. New Caledonia is also home to the world’s 2 most extensive coral reef system. The lagoon between the land and reef crest has been designated a UNESCO World Heritage Site. The present work explores silver nanoparticles discovered during a high-resolution transmission electron microscopy (HR-TEM) based assessment of previously characterized (by other techniques) Ni-rich clay minerals associated with mine waste. These nanoparticles are potentially linked to toxic silver bioaccumulation observed in lagoon organisms [3][4]. This investigation demonstrates the novel data HR-TEM can reveal in geological environmental assessments.

Keywords: silver nanoparticles; microscopy; world heritage; associated mine; world; heritage site

Journal Title: Microscopy and Microanalysis
Year Published: 2018

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