The interaction between gold and oxides plays an important role in developing advanced materials for catalytic, photonic, and microelectronic applications. For example, Au/TiO2 [1] and Au/MgAl2O4 [2] show excellent catalytic… Click to show full abstract
The interaction between gold and oxides plays an important role in developing advanced materials for catalytic, photonic, and microelectronic applications. For example, Au/TiO2 [1] and Au/MgAl2O4 [2] show excellent catalytic activity and Au/CeO2 [3] has tunable reaction selectivity for energy-related reactions. Au/SrTiO3 interface [4] affects the tunneling probability, which is an important characteristic for device design. In spite of their technological importance, the microscopic nature of gold-oxide interfaces, primarily from the interaction between the delocalization of bonding electrons in gold and ionic bonds in oxides, is still a matter of debate.
               
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