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Au nanoparticles (NPs) labeled with handedness tag of "D-" or "L-", which were detached from inorganic chiral silica, showed both intrinsic chirality and SERS-activity. In the presence of these chiral… Click to show full abstract
Au nanoparticles (NPs) labeled with handedness tag of "D-" or "L-", which were detached from inorganic chiral silica, showed both intrinsic chirality and SERS-activity. In the presence of these chiral Au substrates, it was found that the enantiomer of cystine with the same handedness tag of Au NPs would show stronger Raman scattering signal intensities than those of the enantiomer with the opposite tag, where the differences could be over three times. Consequently, this work afforded a novel enantioselective recognition method on ordinary Raman spectroscopy by using chiral plasmonic metallic nanomaterials.
Journal Title: Analytical chemistry
Year Published: 2020
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