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Tuning the Vacancy Concentration in Lithium Germanium Antimony Tellurides—Influence on Phase Transitions, Lithium Mobility, and Thermoelectric Properties

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In the solid solution series Li2–xGe3+1/2xSb2Te7 and Li2–xGe11+1/2xSb2Te15 (0 ≤ x ≤ 2), the heterovalent substitution gradually changes the vacancy concentration on the cation position from 0% (for... Click to show full abstract

In the solid solution series Li2–xGe3+1/2xSb2Te7 and Li2–xGe11+1/2xSb2Te15 (0 ≤ x ≤ 2), the heterovalent substitution gradually changes the vacancy concentration on the cation position from 0% (for...

Keywords: concentration lithium; vacancy concentration; vacancy; tuning vacancy; lithium germanium

Journal Title: Chemistry of Materials
Year Published: 2018

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