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Unravelling the Urea-Route to Boron Nitride: Synthesis and Characterization of the Crucial Reaction Intermediate Ammonium Bis(biureto)borate

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Ammonium bis(biureto)borate, NH4[B(biu)2] (biu = NH–(C═O)–NH–(C═O)–NH), was synthesized as a phase pure powder from urea and triethylborate in a sophisticated solvothermal process. Its crystal stru... Click to show full abstract

Ammonium bis(biureto)borate, NH4[B(biu)2] (biu = NH–(C═O)–NH–(C═O)–NH), was synthesized as a phase pure powder from urea and triethylborate in a sophisticated solvothermal process. Its crystal stru...

Keywords: bis biureto; ammonium bis; biureto borate

Journal Title: Chemistry of Materials
Year Published: 2019

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