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Reactivity and Comprehensive Kinetic Modeling of Deasphalted Vacuum Residue Thermal Cracking

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Upgrading and refining of heavy oil and bitumen has become a costly practice in the last decades, creating a need for new processes to appropriately convert these heavy feedstocks into… Click to show full abstract

Upgrading and refining of heavy oil and bitumen has become a costly practice in the last decades, creating a need for new processes to appropriately convert these heavy feedstocks into lighter and more valuable materials. Solvent deasphalting (SDA) is a carbon rejection process where asphaltenes are removed from the oil using a paraffinic solvent, producing a lighter deasphalted oil (DAO) stream that can be further upgraded without the limitations of asphaltene instabilities. In this work, upgrading via thermal cracking of deasphalted vacuum residue was assessed in a bench scale pilot plant equipped with an up-flow open tubular reactor. Two different feedstocks were evaluated: recycled and virgin DAO. Reactivity experiments were carried out at temperatures within the interval 380–423 °C and liquid hourly space velocities (LHSV) of 0.25–3 h–1. The effects of operating pressure and steam partial pressure on the thermal crackability of DAO were also evaluated as not having a significant effect within the 150...

Keywords: deasphalted vacuum; comprehensive kinetic; vacuum residue; thermal cracking; reactivity comprehensive

Journal Title: Energy & Fuels
Year Published: 2017

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