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Comparison of Catalysts Based on Individual Alkali and Alkaline Earth Metals with Their Composites Used for Steam Gasification of Coal

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One-component catalysts based on alkali and alkaline earth metals (sodium, potassium, and calcium) as well as their composites were applied to the surface of coal samples used in the gasification… Click to show full abstract

One-component catalysts based on alkali and alkaline earth metals (sodium, potassium, and calcium) as well as their composites were applied to the surface of coal samples used in the gasification process. The aim of this work was to compare the impact of these catalysts on the steam gasification of coal by analyzing the results of catalytic and noncatalytic measurements. The use of composites was intended to check whether it is possible to accomplish the synergistic effects (an effect arising between two or more substances interacting together to produce an effect greater than the sum of their individual effects) and overcome the shortcomings of individual metal catalysts. Measurements of steam gasification were conducted by a thermovolumetric method under isothermal conditions at an elevated pressure of 1 × 106 Pa and at four temperatures ranging from 1073 to 1273 K. On the basis of the obtained results, curves of the formation rate of gasification products were developed and yields of main products (hyd...

Keywords: alkali alkaline; catalysts based; steam gasification; coal; gasification; alkaline earth

Journal Title: Energy & Fuels
Year Published: 2017

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