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Effect of Carbonaceous Precursors on the Structure of Mesophase Pitches and Their Derived Cokes

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Using six representative feedstocks as carbonaceous precursors, various mesophase pitches and their derived cokes were obtained by a heat-soaking method at a temperature range of 400–450 °C and a pyrolysis… Click to show full abstract

Using six representative feedstocks as carbonaceous precursors, various mesophase pitches and their derived cokes were obtained by a heat-soaking method at a temperature range of 400–450 °C and a pyrolysis treatment at 900 °C, respectively. The optical texture and microstructure of the different mesophase pitches and their derived cokes were characterized by polarized-light microscope, scanning electron microscope, and X-ray diffraction. The results show that the formation and development abilities of liquid crystalline mesophase are obviously different for the various feedstocks. C9 aromatic hydrocarbons and petroleum-derived paving pitch possess relatively high thermo-chemical reactivity due to the existence of low molecular substances and aliphatic groups, leading to form liquid crystalline mesophase easier and faster than those of naphthalene synthetic pitch and coal tar-based impregnating pitch under a similar condition, which however is undesirable to develop a bulk mesophase. Anthracene possesses a...

Keywords: mesophase pitches; derived cokes; carbonaceous precursors; pitches derived; mesophase; effect carbonaceous

Journal Title: Energy & Fuels
Year Published: 2018

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