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Effect of Nanopore Confinement on Crude Oil Thermal-Oxidative Behavior

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The AIP (air injection process) could be a promising technique to develop shale oil reservoirs because air has immense availability and free resources. The main differences between the AIP and… Click to show full abstract

The AIP (air injection process) could be a promising technique to develop shale oil reservoirs because air has immense availability and free resources. The main differences between the AIP and conventional gas injection techniques are attributed to the complicated reactions among air, crude oil, and rock. The catalytic effect of the clay minerals on crude oil thermal-oxidative characteristics has been extensively studied; however, the confinement effect has rarely been discussed. In this study, the confinement effect of nanoscale porous media on crude oil thermal-oxidative characteristics was investigated using TGA (thermogravimetric analyzer) and DSC (differential scanning calorimetry) experiments, where the confinement environment was provided by the CPGs (controlled pore glasses). CPGs with three different pore sizes of 51, 85, and 172 nm were used. Also, the Arrhenius method was applied to investigate the crude oil oxidation kinetics during the AIP. The experimental results show that the confinement e...

Keywords: effect; thermal oxidative; crude oil; oil; oil thermal

Journal Title: Energy & Fuels
Year Published: 2018

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