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Rheological Behavior of Surface Modified Silica Nanoparticles Dispersed in Partially Hydrolyzed Polyacrylamide and Xanthan Gum Solutions: Experimental Measurements, Mechanistic Understanding, and Model Development

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Polymer solutions are designed to develop a favorable mobility ratio between the injected polymer solution and the oil–water bank being displaced by the polymer. Subsequently, a more uniform volumetric sweep… Click to show full abstract

Polymer solutions are designed to develop a favorable mobility ratio between the injected polymer solution and the oil–water bank being displaced by the polymer. Subsequently, a more uniform volumetric sweep of the reservoir is produced. Chemical and mechanical degradation of the polymer solutions, on the other hand, reduce their viscosity which significantly affects their performance. The primary objective of this study is to investigate the effect of surface modification of silica nanoparticles (NPs) on the effective viscosity of partially hydrolyzed polyacrylamide (HPAM) and xanthan gum (XG) solutions at different NP concentrations and temperatures. The chemical functionalization of SiO2 NPs with carboxylic acids and silanes was confirmed by FTIR measurements. The experimental results showed that the addition of SiO2 NPs increased the viscosity of XG solutions due to the formation of three-dimensional structures between the silica NPs and the polymeric chains. The thickening effect of HPAM was improved...

Keywords: gum solutions; surface; silica nanoparticles; xanthan gum; hydrolyzed polyacrylamide; partially hydrolyzed

Journal Title: Energy & Fuels
Year Published: 2018

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