LAUSR

Recently, researchers at West Virginia University reported a promising catalyst innovation for nonoxidative thermochemical conversion of methane to CO2-free hydrogen and solid carbon nanotubes (CNTs). A catalyst system was discovered that promotes “base growth” CNT formation rather than conventional “tip growth”. This enables catalyst regenerability while also generating highly pure and crystalline carbon products. In this study, simultaneous productions of CNTs and CO2-free hydrogen were studied over Fe-based catalysts supported on Al2O3, SiO2, and H-ZSM-5. The experimental results showed that metal–support interaction played a key role in the base growth mechanism. Methane conversion and the property of CNTs depended significantly on metal loading and the type of support. To elucidate the formation mechanism of CNTs, the spent catalysts were characterized by a number of analytical instrumentations including transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD)...