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Sampling Dissolved Gases in Groundwater at in Situ Pressure: A Simple Method for Reducing Uncertainty in Hydrogeological Studies of Coal Seam Gas Exploration

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The ability to accurately and precisely measure dissolved gas concentrations in groundwater is crucial for environmental monitoring purposes. Unfortunately, the collection of dissolved gas samples in groundwater is challenging because… Click to show full abstract

The ability to accurately and precisely measure dissolved gas concentrations in groundwater is crucial for environmental monitoring purposes. Unfortunately, the collection of dissolved gas samples in groundwater is challenging because of the loss of dissolved gas in the groundwater as a result of inadequate sampling methodologies and the need to avoid exposure of the samples to the atmosphere. In environments where water can contain large amounts of methane and carbon dioxide (e.g., coal basins), there is a high probability of separation between the water and gas phases during sample collection, making it impossible to accurately measure the gas concentrations in a groundwater sample. In this paper, we describe the design and development of a novel downhole sampler that is used to collect dissolved gas samples in groundwater at in situ pressure. The sampler was used to collect samples from 26 bores in a proposed coal seam gas field in regional New South Wales, Australia. Comparison of CH4 concentration da...

Keywords: seam gas; coal seam; situ pressure; gas; dissolved gas; groundwater situ

Journal Title: Environmental Science and Technology Letters
Year Published: 2017

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