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Viscosities of Pure Ionic Liquids Using Combinations of Free Volume Theory or Friction Theory with the Cubic, the Cubic Plus Association, and the Perturbed-Chain Statistical Associating Fluid Theory Equations of State at High Pressures

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In this study, the behaviors of viscosities of nine ionic liquids (ILs) over wide ranges of pressures and temperatures were determined. The investigated ILs belonged to the three imidazolium-based families… Click to show full abstract

In this study, the behaviors of viscosities of nine ionic liquids (ILs) over wide ranges of pressures and temperatures were determined. The investigated ILs belonged to the three imidazolium-based families of tetrafluoroborate, hexafluorophosphate, and bis[(trifluoromethyl)sulfonyl]imide. The two well-known cubic equations of state (EoS’s) of Peng–Robinson (PR) and the Soave–Redlich–Kwong (SRK), as well as the two more-sophisticated EoS’s of cubic plus association (CPA), and perturbed-chain statistical associating fluid theory (PC-SAFT), were each coupled with two well-known theoretical viscosity models, namely the friction theory and the free volume theory. Calculated results showed that the free volume model, coupled with PC-SAFT, has superior results in comparison to the free volume model with the CPA EoS. For the viscosity model of free volume, the studied cubic EoS’s did not give accurate results. When the friction model was used, the PC-SAFT EoS once more showed better accuracy than the CPA EoS; how...

Keywords: equations state; theory; free volume; ionic liquids; cubic plus

Journal Title: Industrial & Engineering Chemistry Research
Year Published: 2017

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