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Fabrication of Ecofriendly Recycled Marimo-like Hierarchical Micronanostructure Superhydrophobic Materials for Effective and Selective Separation of Oily Pollutants from Water

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Marimo-like hierarchical micronanostructure superhydrophobic β-FeOOH (MHMSFe) firmly anchored onto the skeleton of sponge/cotton fabric (MHMSFe@sponge/MHMSFe@cotton fabric) as superhydrophobic materials were successfully designed and fabricated via a one-step surfactant and urea-assisted… Click to show full abstract

Marimo-like hierarchical micronanostructure superhydrophobic β-FeOOH (MHMSFe) firmly anchored onto the skeleton of sponge/cotton fabric (MHMSFe@sponge/MHMSFe@cotton fabric) as superhydrophobic materials were successfully designed and fabricated via a one-step surfactant and urea-assisted hydrothermal method. By the combination of micronanostructure design, a three-dimensional (3D) hierarchical architecture was built from spherical assembly of high integration and density superhydrophobic β-FeOOH nanorods, which tended to stack up to each other in an orderly manner to decrease their surface energy. The obtained superhydrophobic materials with a static contact angle (CA) of 168° could not only undergo rapid oil/water separation but also display excellent absorption capacity up to 23 times of its own weight and great separation efficiency up to 99.6%. Besides, the superhydrophobic materials performed satisfactory reusability. This study not only provides a new strategy to design superhydrophobic materials bu...

Keywords: superhydrophobic materials; separation; like hierarchical; hierarchical micronanostructure; micronanostructure; marimo like

Journal Title: Industrial & Engineering Chemistry Research
Year Published: 2019

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