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Unsymmetrical trifluoro functional groups were installed onto metal-organic frameworks (MOFs) at positions regulated by ligand exchange for efficient CO2 separation under humid conditions. These trifluoro groups induced molecular separation via… Click to show full abstract
Unsymmetrical trifluoro functional groups were installed onto metal-organic frameworks (MOFs) at positions regulated by ligand exchange for efficient CO2 separation under humid conditions. These trifluoro groups induced molecular separation via dipole-dipole interactions. Their installation onto amino-functionalized MOF surfaces produced hydrophobic and CO2-philic core-shell MOFs for efficient CO2 adsorption.
Keywords:
onto metal;
metal organic;
separation;
humid conditions;
organic frameworks;
separation humid
Journal Title: Inorganic chemistry
Year Published: 2020
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!