Photo by vlisidis from unsplash
The reactions of ReI3, Se, and KCN with Sb2O3 or Bi2O3 at elevated temperature led to the formation of two new tetrahedral clusters with mixed-ligand cluster cores {Re4Se3Sb}7+ and {Re4Se3Bi}7+.… Click to show full abstract
The reactions of ReI3, Se, and KCN with Sb2O3 or Bi2O3 at elevated temperature led to the formation of two new tetrahedral clusters with mixed-ligand cluster cores {Re4Se3Sb}7+ and {Re4Se3Bi}7+. They are the first examples of complexes with either Sb3- or Bi3- ligands, which have never been previously described in the literature.
Keywords:
re4se3sb re4se3bi;
ligand cluster;
cores re4se3sb;
cluster cores;
mixed ligand;
sb3 bi3
Journal Title: Inorganic chemistry
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Inorganic chemistry
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!