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Dipyridyl-Decorated Nitronyl Nitroxide-DyIII Single-Molecule Magnet with a Record Energy Barrier of 146 K.

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A nitronyl nitroxide biradical with a capping N-donor group was discovered to improve single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K. As far as… Click to show full abstract

A nitronyl nitroxide biradical with a capping N-donor group was discovered to improve single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K. As far as we know, the effective energy barrier of the Dy compound is largest in the nitronyl nitroxide 4f system by far.

Keywords: nitronyl nitroxide; energy barrier; barrier; single molecule; barrier 146; molecule magnet

Journal Title: Inorganic chemistry
Year Published: 2021

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