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Borylated triazenes were synthesized by the dehydrocoupling of triazenes with 9-borabicyclo(3.3.1)nonane, by the condensation of triazenes with BEt3, or by the reaction of sodium triazenides with dialkyl- or diarylboron halides.… Click to show full abstract
Borylated triazenes were synthesized by the dehydrocoupling of triazenes with 9-borabicyclo(3.3.1)nonane, by the condensation of triazenes with BEt3, or by the reaction of sodium triazenides with dialkyl- or diarylboron halides. The structures of the products were found to depend on the size of the substituents. Sterically demanding mesityl groups at boron or nitrogen gave rise to open-chain structures, whereas smaller substituents led to the formation of novel BN3 heterocycles.
Keywords:
four membered;
heterocycles borylation;
membered bn3;
bn3;
synthesis four;
bn3 heterocycles
Journal Title: Inorganic chemistry
Year Published: 2022
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Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!