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A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring… Click to show full abstract
A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.
Keywords:
barium borate;
possible deep;
h3bo3 h2o;
barium;
ba2b10o16 h3bo3
Journal Title: Inorganic chemistry
Year Published: 2022
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Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!