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A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen… Click to show full abstract
A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to produce up to 371 equiv of silylamine based on the cobalt atom of the catalyst.
Keywords:
dinitrogen complexes;
cobalt;
bearing anionic;
complexes bearing;
cobalt dinitrogen;
dinitrogen
Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!