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Enhanced Interlayer Interaction and Second-Harmonic-Generation Response in a KBe2BO3F2-Type Inorganic-Organic Hybrid Zinc Borate.

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A new inorganic-organic hybrid zinc borate was prepared under hydrothermal conditions. This compound is the first KBe2BO3F2 (KBBF) derivative with zinc borate layers linked by mononegatively charged amino acids. Notably,… Click to show full abstract

A new inorganic-organic hybrid zinc borate was prepared under hydrothermal conditions. This compound is the first KBe2BO3F2 (KBBF) derivative with zinc borate layers linked by mononegatively charged amino acids. Notably, it exhibits a relatively large second-harmonic-generation response of about 2.0 times that of KBBF and a moderate birefringence for phase matching in the UV region. The enhanced interlayer interaction was evaluated by theoretical calculations based on density functional theory.

Keywords: zinc; zinc borate; hybrid zinc; organic hybrid; inorganic organic

Journal Title: Inorganic chemistry
Year Published: 2022

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