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Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with… Click to show full abstract
Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed, affording unprecedented B(6)-phosphinated nido-carborane derivatives with high selectivity in a simple one-pot process.
Keywords:
cascade deboronation;
phosphorization nido;
nido;
carboranes via;
via cascade;
nido carboranes
Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!