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Rhenium(I)-Based Neutral Coordination Cages with a Spherical Cavity for Selective Recognition of Fluoride.

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Neutral heteroleptic trinuclear coordination cages containing a preorganized well-defined small spherical endocavity, which is made up of electron-deficient bowl frameworks, three coordination-induced neutral polar C-H donors, and a phenyl motif,… Click to show full abstract

Neutral heteroleptic trinuclear coordination cages containing a preorganized well-defined small spherical endocavity, which is made up of electron-deficient bowl frameworks, three coordination-induced neutral polar C-H donors, and a phenyl motif, were self-assembled via a one-pot approach; the endocavity accommodates fluoride selectively in the presence of other halides.

Keywords: neutral coordination; based neutral; coordination; coordination cages; rhenium based; cages spherical

Journal Title: Inorganic chemistry
Year Published: 2022

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