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An unprecedented metal-linked cluster-based coordination polymer, composed of heniconuclear {Mn21} clusters and Mn(II) ions as the nodes and linkers, respectively, was self-assembled from a facile aqueous synthesis. The structural analysis… Click to show full abstract
An unprecedented metal-linked cluster-based coordination polymer, composed of heniconuclear {Mn21} clusters and Mn(II) ions as the nodes and linkers, respectively, was self-assembled from a facile aqueous synthesis. The structural analysis reveals that the compound possesses a rare 3D 8-connected hex framework topology. Significantly, the compound demonstrates a high proton conductivity of 1.06 mS cm-1 at 373 K and 98% RH and exhibits a magnetocaloric effect with a magnetic entropy change of -9.94 J kg-1 K-1 at H = 80 kOe and T = 6.0 K.
Journal Title: Inorganic chemistry
Year Published: 2022
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