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Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation… Click to show full abstract
Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.
Keywords:
photooxidation;
frameworks efficient;
lanthanide anderson;
anderson;
anderson polyoxometalates;
polyoxometalates frameworks
Journal Title: Inorganic chemistry
Year Published: 2022
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Journal Title: Inorganic chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!