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The development of multi-functional materials as physical adsorbents for gas storage and dye adsorption is of utmost importance for ecological environment management. Ionic metal-organic frameworks (MOFs) with exchangeable counterions would… Click to show full abstract
The development of multi-functional materials as physical adsorbents for gas storage and dye adsorption is of utmost importance for ecological environment management. Ionic metal-organic frameworks (MOFs) with exchangeable counterions would easily be modified to enhance their performance. Herein, we report a novel {Zn5}-based MOF (SDU-CP-2) with the dimethylamine cation [(CH3)2NH2]+ in its crystal structure, which can be readily exchanged with Li+ ions and cationic dyes. Consequently, it exhibits high CO2 and C2H2 adsorption capacities as well as charge/size-selective adsorption of dye molecules. The adsorption of SDU-CP-2 toward cationic dyes was confirmed to be efficient in terms of recyclability and ion-exchange mechanisms. The column filler experiment and high water stability decisively supported its potential application in waste water treatment.
Journal Title: Inorganic chemistry
Year Published: 2022
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