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Herein we report two tubular metal-organic cages (MOCs), synthesized by the self-assembly of bidentate metalloligands with different lengths and PdII. These two MOCs feature Pd4L8-type square tubular and Pd3L6-type triangular… Click to show full abstract
Herein we report two tubular metal-organic cages (MOCs), synthesized by the self-assembly of bidentate metalloligands with different lengths and PdII. These two MOCs feature Pd4L8-type square tubular and Pd3L6-type triangular cage structures, respectively. Both MOCs have been fully characterized by NMR spectroscopy, mass spectrometry, and theoretical calculation. Both cages can be employed for encapsulating polycyclic aromatic hydrocarbons and show high binding affinity toward coronene.
Keywords:
aromatic hydrocarbons;
self assembly;
organic cages;
polycyclic aromatic;
assembly two;
two tubular
Journal Title: Inorganic chemistry
Year Published: 2023
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2023
Link to full text (if available)
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recommendations!