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Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were accessed by reactions of a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. While 1,2-diboratabenzene metal complexes are… Click to show full abstract
Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were accessed by reactions of a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. While 1,2-diboratabenzene metal complexes are known, these represent the first examples of the ligand bridging two metals.
Keywords:
bridging diboratabenzene;
iron cobalt;
decker iron;
cobalt complexes;
triple decker;
diboratabenzene ligand
Journal Title: Inorganic chemistry
Year Published: 2023
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Journal Title: Inorganic chemistry
Year Published: 2023
Link to full text (if available)
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recommendations!