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Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones.

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Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit.… Click to show full abstract

Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.

Keywords: light harvesting; containing light; rhodium; fluorene backbones; harvesting fluorene; synthesis mono

Journal Title: Inorganic chemistry
Year Published: 2017

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