Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit.… Click to show full abstract
Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.
               
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