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Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure-temperature phase diagram of Co[N(CN)2]2. The second-order… Click to show full abstract
Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure-temperature phase diagram of Co[N(CN)2]2. The second-order structural boundaries converge on key areas of activity involving the spin state exposing how the pressure-induced local lattice distortions trigger the ferromagnetic → antiferromagnetic transition in this quantum material.
Keywords:
pressure temperature;
temperature phase;
pressure;
phase diagram
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
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recommendations!