Photo by vlisidis from unsplash
Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring… Click to show full abstract
Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co length shorter than ∼10.9 Å, resulting in a field-induced metamagnetic transition, while being absent over lengths longer than ∼14.7 Å.
Keywords:
length;
coupling porous;
antiferromagnetic coupling;
control interchain;
porous based;
interchain antiferromagnetic
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!