Photo by vlisidis from unsplash
Cubic and highly porous [Mn(2-methylimidazolate)2] (Mn-ZIF-8) was synthesized from [Mn(BH4)2·3THF]·NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger… Click to show full abstract
Cubic and highly porous [Mn(2-methylimidazolate)2] (Mn-ZIF-8) was synthesized from [Mn(BH4)2·3THF]·NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)2]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal-organic framework systems.
Keywords:
zif bh4;
manganese zif;
bh4 3thf;
synthesis manganese;
3thf nabh4
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!