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A new metal polyphosphate, α-CsBa2(PO3)5, exhibiting the first example of a linear P-O-P bond angle in a one-dimensional (PO3)∞ chain has been reported. Interestingly, α → β phase transition occurs… Click to show full abstract
A new metal polyphosphate, α-CsBa2(PO3)5, exhibiting the first example of a linear P-O-P bond angle in a one-dimensional (PO3)∞ chain has been reported. Interestingly, α → β phase transition occurs in CsBa2(PO3)5 along with the P-O-P bonds varying from linear to λ-shape, suggesting that α-CsBa2(PO3)5 with unfavorable linear P-O-P bonds is more stable at ambient temperature.
Keywords:
po3 chain;
bond;
linear shape;
po3
Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!