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The title compound was prepared upon irradiation of acetonitrile solutions of the readily available hexacarbonyl [MoReCp(μ-H)(μ-PCy2)(CO)6]. The acetonitrile ligand in this compound could be replaced easily by donor molecules or… Click to show full abstract
The title compound was prepared upon irradiation of acetonitrile solutions of the readily available hexacarbonyl [MoReCp(μ-H)(μ-PCy2)(CO)6]. The acetonitrile ligand in this compound could be replaced easily by donor molecules or displaced upon two-electron reduction. In most cases, the substitution step was followed by additional processes such as insertion into the M-H bonds, E-H bond cleavage, H2 elimination, and other transformations.
Keywords:
morecp;
morecp pcy2;
adduct morecp;
pcy2 ncme;
acetonitrile adduct
Journal Title: Inorganic chemistry
Year Published: 2018
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2018
Link to full text (if available)
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recommendations!