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Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range.

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We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis(ethylenedioxo)tetrathiafulvalene], whose conductivity and single-molecule magnetism coexist in the same temperature range. The compound was synthesized by BEDO… Click to show full abstract

We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis(ethylenedioxo)tetrathiafulvalene], whose conductivity and single-molecule magnetism coexist in the same temperature range. The compound was synthesized by BEDO electrocrystallization in the presence of (Ph4P)2[ReF6]·2H2O and characterized by crystallography and measurements of the conductivity and alternating-current magnetic susceptibility.

Keywords: molecule; temperature range; single molecule; conductivity single; molecule magnetism

Journal Title: Inorganic chemistry
Year Published: 2018

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