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We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium(II) carboxylate metal-organic frameworks (i.e., Cr3(BTC)2·3H2O (1) and Cr(hfipbb)·H2O (2) at room temperature in water. Both MOFs can… Click to show full abstract
We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium(II) carboxylate metal-organic frameworks (i.e., Cr3(BTC)2·3H2O (1) and Cr(hfipbb)·H2O (2) at room temperature in water. Both MOFs can be easily dehydrated, affording single-crystalline materials with open Cr(II) sites. In addition, the redox activity and porosity of the resulting Cr(II) MOFs were examined.
Keywords:
carboxylate;
straightforward synthesis;
synthesis single;
redox;
single crystalline;
crystalline
Journal Title: Inorganic chemistry
Year Published: 2018
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Journal Title: Inorganic chemistry
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!