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We report about the coordination-driven self-assembly of a chiral bis-pyridyl ligand (1), synthesized from steroidal cholic acid, with Pd(II) ions to form a chiral metal-organic Pd2(1)4 cage. The self-assembly of… Click to show full abstract
We report about the coordination-driven self-assembly of a chiral bis-pyridyl ligand (1), synthesized from steroidal cholic acid, with Pd(II) ions to form a chiral metal-organic Pd2(1)4 cage. The self-assembly of the cage was facilitated by favorable conformational change in the alkyl chain of the cholic acid. Interligand hydrogen bonding played a crucial role in directing the formation of a C4 symmetric cage among different possible isomers, as suggested by DFT studies, and control experiments with different ligands.
Journal Title: Inorganic chemistry
Year Published: 2019
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