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Flexible-Ligand-Based Self-adaptive Metal-Organic Material for Supramolecular Selective Recognition of Similar Natural Molecules.

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A flexible-ligand-based metal-organic cage containing functional amide and secondary amino groups as guest-interacted sites has been synthesized. The synergistic effect between the size-defined cavity and self-adaptive backbone endows the cage… Click to show full abstract

A flexible-ligand-based metal-organic cage containing functional amide and secondary amino groups as guest-interacted sites has been synthesized. The synergistic effect between the size-defined cavity and self-adaptive backbone endows the cage excellent properties for the selective recognition of specific natural guests over other similar molecules via fluorescent response.

Keywords: ligand based; selective recognition; self adaptive; metal organic; flexible ligand

Journal Title: Inorganic chemistry
Year Published: 2019

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