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White-light emission with CIE (0.32, 0.34) was realized for an o-terphenyl (oTP) molecule in its Ag3[3,5-(CF3)2Pz]3 (Pz = pyrazolate) sandwiching adduct, originating from the hybrid of fluorescence and sensitized long-afterglow… Click to show full abstract
White-light emission with CIE (0.32, 0.34) was realized for an o-terphenyl (oTP) molecule in its Ag3[3,5-(CF3)2Pz]3 (Pz = pyrazolate) sandwiching adduct, originating from the hybrid of fluorescence and sensitized long-afterglow phosphorescence of oTP. Density functional theory (DFT) and time-dependent DFT calculations revealed that heavy-atom effects of Ag play a crucial role in sensitization of the triplet of oTP, giving off its ultralong phosphorescence.
Keywords:
phosphorescence;
terphenyl;
long afterglow;
afterglow phosphorescence;
fluorescence sensitized;
white light
Journal Title: Inorganic chemistry
Year Published: 2019
Link to full text (if available)
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Journal Title: Inorganic chemistry
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!