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Interpreting the Operando XANES of Surface-Supported Subnanometer Clusters: When Fluxionality, Oxidation State, and Size Effect Fight

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X-ray absorption near edge structure (XANES) spectroscopy is widely used for operando catalyst characterization. We show that, for highly fluxional supported nanoclusters, the customary extraction ... Click to show full abstract

X-ray absorption near edge structure (XANES) spectroscopy is widely used for operando catalyst characterization. We show that, for highly fluxional supported nanoclusters, the customary extraction ...

Keywords: subnanometer clusters; surface supported; supported subnanometer; operando xanes; xanes surface; interpreting operando

Journal Title: Journal of Physical Chemistry C
Year Published: 2020

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