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Ligand Effects on the Structures of [Au23L6(C≡CPh)9]2+ (L = N-Heterocyclic Carbene vs Phosphine) with Au17 Superatomic Cores

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A new gold cluster compound [Au23(NHCptol)6(C≡CPh)9]2+ (NHCptol = 1,3-di(para-methylbenzyl)benzimidazolin-2-ylidene) (Au23NHCptol) was synthesized, and its geometric and electronic structures were ... Click to show full abstract

A new gold cluster compound [Au23(NHCptol)6(C≡CPh)9]2+ (NHCptol = 1,3-di(para-methylbenzyl)benzimidazolin-2-ylidene) (Au23NHCptol) was synthesized, and its geometric and electronic structures were ...

Keywords: effects structures; au23l6 cph; cph heterocyclic; ligand effects; heterocyclic carbene; structures au23l6

Journal Title: Journal of Physical Chemistry C
Year Published: 2021

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