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Sandwich-Structured PVDF-Based Composite Incorporated with Hybrid Fe3O4@BN Nanosheets for Excellent Dielectric Properties and Energy Storage Performance

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High-performance energy storage materials are of essential importance in advanced electronics and pulsed power systems, and the polymer dielectrics have been considered as a promising energy storage material, because of… Click to show full abstract

High-performance energy storage materials are of essential importance in advanced electronics and pulsed power systems, and the polymer dielectrics have been considered as a promising energy storage material, because of its higher dielectric strength and more excellent flexibility compared with that of inorganic ceramic dielectrics. However, the energy storage capability of pristine polymer has been limited by its low intrinsic dielectric permittivity and ordinary ferroelectric performance. Herein, this work demonstrates a favorable method to achieve a sandwich-structured poly(vinylidene fluoride) (PVDF)-based composite by the electrospinning, solution casting, thermal quenching, and hot-pressing process. This innovative method combines with the 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 nanofibers (BZT-BCT NFs), which possesses good ferroelectric hysteresis, and the hybrid particles of hexagonal boron nitride nanosheets (BNNSs) coated by ferroferric oxide (Fe3O4@BNNSs), which hold high breakdown strength (E...

Keywords: pvdf based; sandwich structured; energy; energy storage; performance

Journal Title: Journal of Physical Chemistry C
Year Published: 2018

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