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Streaming Potential with Ideally Polarizable Electron-Conducting Substrates

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With nonconducting substrates, streaming potential in sufficiently broad (vs Debye screening length) capillaries is well known to be a linear function of applied pressure (and coordinate along the capillary). This… Click to show full abstract

With nonconducting substrates, streaming potential in sufficiently broad (vs Debye screening length) capillaries is well known to be a linear function of applied pressure (and coordinate along the capillary). This study for the first time explores streaming potential with ideally polarizable electron-conducting substrates and shows it to be a nonlinear function of both coordinate and applied pressure. Experimental manifestations can be primarily expected for streaming potentials arising along thin porous electron-conducting films experiencing solvent evaporation from the film side surface. Model predictions are in good qualitative agreement with literature experimental data.

Keywords: streaming potential; ideally polarizable; potential ideally; polarizable electron; electron conducting

Journal Title: Langmuir
Year Published: 2022

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