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Synthesis and Properties of Gradient Copolymers Composed of Norbornene and Higher α-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] Catalyst System

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The copolymerization of norbornene (NB) and various α-olefins [1-octene (O), 1-decene (De), and 1-dodecene (Do)] was achieved with high activity using (tBuNSiMe2Flu)TiMe2 (1)-[Ph3C][B(C6F5)4] and 2... Click to show full abstract

The copolymerization of norbornene (NB) and various α-olefins [1-octene (O), 1-decene (De), and 1-dodecene (Do)] was achieved with high activity using (tBuNSiMe2Flu)TiMe2 (1)-[Ph3C][B(C6F5)4] and 2...

Keywords: gradient copolymers; synthesis properties; ph3c; ph3c c6f5; properties gradient

Journal Title: Macromolecules
Year Published: 2020

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